Amphoteric Aqueous Hafnium Cluster Chemistry

Fenton chemistry at aqueous interfaces.

In a fundamental process throughout nature, reduced iron unleashes the oxidative power of hydrogen peroxide into reactive intermediates. However, notwithstanding much work, the mechanism by which Fe(2+) catalyzes H2O2 oxidations and the identity of the participating intermediates remain controversial. Here we report the prompt formation of O=Fe(IV)Cl3(-) and chloride-bridged di-iron O=Fe(IV) · ...

Amphoteric Colloids

1. When we plot the values of osmotic pressure, swelling, and viscosity of gelatin solutions as ordinates over the pH as abscissae, practically identical curves are obtained for the effect of monobasic acids (HCl, HBr, HNO(3), and acetic acid) on these properties. 2. The curves obtained for the effect of H(2)SO(4) on gelatin are much lower than those obtained for the effect of monobasic acids, ...

Preparation and Characterization of Amphoteric Cellulose Hydrogels as Adsorbents for the Anionic Dyes in Aqueous Solutions

A series of cellulose ampholytes (CAms), with substitution degrees of cationic groups (DSC) of 0.41, 0.79, and 1.08, and with a substitution degree of anionic groups of 0.68, was prepared from sodium carboxymethylcellulose by a cationization reaction with 2,3-epoxypropyltrimethylammonium chloride. The obtained CAms were crosslinked by ethyleneglycoldiglycidylether (EGDE) to obtain cellulose pol...

Raman spectroscopic study of the structure of water in aqueous solutions of amphoteric polymers.

Methacrylic acid (MA) and [3-(methacryloylamino)propyl]trimethylammonium chloride (MAPTAC) were polymerized to give amphoteric copolymers with various compositions. The structure and H-bonding of water in an aqueous solution of the copolymer were analyzed using the contours of the O-H stretching in the polarized Raman spectra. For comparison, the H-bonded network structure of aqueous solutions ...

Aqueous Solution Surface Chemistry of Carbon Nanotubes